Thermally insulating carbon nanotubes and copper ferrite based porous polydimethylsiloxane foams for absorption-dominant electromagnetic interference shielding performance

The exponential growth of the electronic and communication industry in the last 50 years raised serious concerns about electromagnetic (EM) pollution. Consequently, suitable composite materials for electromagnetic interference (EMI) shielding have been developed to reduce EM pollution. In the present work, carbon nanotubes (CNT) and copper ferrite (CuFe2O4) nanoparticle-based porous polydimethylsiloxane (PDMS) composite foams were prepared using the baking soda template method. The PDMS foam acts as the 3-dimensional (3D) porous network, CNT gives the required conductive path and magnetic CuFe2O4 provides the necessary magnetic loss, so that the resultant foams achieved high EMI shielding through the absorption mechanism. Without the inclusion of CuFe2O4, the total EMI SE of the PDMS foam is lower than 20 dB, while various contents of the added CuFe2O4 improve the EMI SE up to 32 dB at a thickness of 3 mm. In addition, the thermal insulation properties are also reported and the resultant material shows a moderately low thermal conductivity of 0.046 W m−1 K−1. These characteristics of the composite foam highlight the strong absorption-dominated EMI shielding and thermal insulation performance, allowing it to successfully meet a wide range of applications.