光子上转换
化学
芳基
光化学
猝灭(荧光)
光催化
催化作用
光催化
组合化学
亲核细胞
荧光
有机化学
烷基
离子
物理
量子力学
作者
Jorge Castellanos-Soriano,Daniel Álvarez-Gutiérrez,M. Consuelo Jiménez,Raúl Pérez‐Ruiz
标识
DOI:10.1007/s43630-022-00203-5
摘要
Abstract In this work, the feasibility of triplet fusion upconversion ( TFU , also named triplet–triplet annihilation upconversion) technology for the functionalization (arylation) of furans and thiophenes has been successfully proven. Activation of aryl halides by TFU leads to generation of aryl radical intermediates; trapping of the latter by the corresponding heteroarenes, which act as nucleophiles, affords the final coupling products. Advantages of this photoredox catalytic method include the use of very mild conditions (visible light, standard conditions), employment of commercially available reactants and low-loading metal-free photocatalysts, absence of any sacrificial agent (additive) in the medium and short irradiation times. The involvement of the high energetic delayed fluorescence in the reaction mechanism has been evidenced by quenching studies, whereas the two-photon nature of this photoredox arylation of furans and thiophenes has been manifested by the dependence on the energy source power. Finally, the scaling-up conditions have been gratifyingly afforded by a continuous-flow device. Graphical abstract
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