过硫酸盐
苯酚
化学
铁质
催化作用
电子转移
硫化物
生物炭
无机化学
吸附
光化学
有机化学
热解
作者
Jianhua Qu,Yangsheng Xu,Xiubo Zhang,Mingze Sun,Yue Tao,Xinmiao Zhang,Guangshan Zhang,Chengjun Ge,Ying Zhang
标识
DOI:10.1016/j.apcatb.2022.121639
摘要
Designing Fe-carbon catalyst with multiple active sites for persulfate (PS) activation to water purification is challenging. Herein, nitrogen-doped biochar (NBC) loaded with ferrous sulfide (FeS) was synthesized via two-step ball milling. In FeS@NBCBM/PS system, both electron transfer process and reactive oxygen species (ROSs) including SO4⋅−, O⋅H, O2•− and 1O2 contributed to phenol degradation. Surface-bound S(II) not only interacted with PS for generating SO4•−, but also accelerated Fe(III)/Fe(II) circulation by reducing Fe(III). NBC was favorable for phenol adsorption and exposure of oxygen-containing groups, graphitic and pyridinic N active sites, which mediated electron transfer or ROSs formation. Owing to multiple active sites, this system fast achieved almost complete phenol degradation with excellent adaptability to wide pH range of 3–9, high anti-interference capacity to coexisting substances, and was efficient to various water matrices. Furthermore, phenol degradation pathways were elucidated by DFT calculations with intermediate products showing lower toxicity, demonstrating great potentials of proposed system.
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