电解质
材料科学
无定形固体
电极
离子键合
化学工程
涂层
离子
纳米技术
聚合物
快离子导体
储能
泄漏(经济)
离子电导率
电化学
复合材料
化学
经济
功率(物理)
物理化学
有机化学
量子力学
宏观经济学
工程类
物理
作者
Anirudha Jena,Yedukondalu Meesala,Shu Fen Hu,Ho Chang,Ru‐Shi Liu
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2018-10-05
卷期号:3 (11): 2775-2795
被引量:65
标识
DOI:10.1021/acsenergylett.8b01564
摘要
Li-ion batteries (LIBs) are a class of electrochemical energy storage devices widely adapted for their versatile use. Commercialized liquid electrolyte-based batteries are developing various issues like explosions, limited energy density, and leakage. All-solid-state batteries (ASSBs) with Li-ion-containing solid electrolytes (SEs) can be a solution to these shortcomings. However, assembling ASSBs is a challenge due to the high interfacial resistance between the electrodes and SEs. In the current Review, we addressed the rising concern over the interfacial deterioration leading to high charge-transfer resistance. A comprehensive discussion on the addition of buffer layers between the SE and electrodes is presented to improve interfacial stability. From polymer layers containing Li-salts with and without supporting fillers to amorphous oxides and metal coating, the interlayers ameliorate the ionic transport. Mutual compression and cosintering of SEs and electrodes can make a compact interface. Finally, the influence of morphology at the contacting surfaces is discussed.
科研通智能强力驱动
Strongly Powered by AbleSci AI