非随机双液模型
溶解度
冰片
樟脑
差示扫描量热法
丙酮
热力学
溶剂
化学
活度系数
材料科学
分析化学(期刊)
色谱法
物理化学
有机化学
物理
水溶液
病理
中医药
替代医学
医学
作者
Jingjing Chen,Jingjing He,Ningxin Li,Huidong Zheng,Suying Zhao
标识
DOI:10.1021/acs.jced.9b00045
摘要
The solubility of borneol, camphor, and isoborneol in four solvents (i.e., acetone, ethanol, p-cymene, and p-xylene) was measured by the static equilibrium method within the temperature range of 296.65–348.85 K under the atmosphere. The fusion points and fusion enthalpies of borneol and isoborneol were determined by differential scanning calorimetry. The Apelblat equation, Wilson model, and NRTL model were employed to correlate the measured solubility data, and the NRTL model fits the measured data better. Mixing properties of each solute–solvent pair are calculated by the NRTL model.
科研通智能强力驱动
Strongly Powered by AbleSci AI