A novel ball-milled aluminum-carbon composite for enhanced adsorption and degradation of hexabromocyclododecane

Hexabromocyclododecane (HBCD) is one of the priority persistent organic pollutants (POPs), yet a cost-effective technology has been lacking for the removal and degradation of HBCD. Zero-valent aluminum (ZVAl) is an excellent electron donor. However, the inert and hydrophilic surface oxide layer impedes the release of the electrons from the core metallic Al, resulting in poor reactivity towards HBCD. In this research, a new type of modified mZVAl particles (AC@mZVAl bm/NaCl ) were prepared through ball milling mZVAl in the presence of activated carbon (AC) and NaCl, and tested for adsorption and reductive degradation of HBCD in water. AC@mZVAl bm/NaCl was characterized with a metallic Al core with newly created reactive surface coated with a thin layer of crushed carbon nanoparticles. AC@mZVAl bm/NaCl was able to rapidly (within 1 h) adsorb HBCD (C 0 = 2 mg L −1 ) and thus effectively enriched HBCD on the carbon surface of AC@mZVAl bm/NaCl . The pre-enriched HBCD was subsequently degraded by the electrons from the core Al, and ∼63.44% of the pre-sorbed HBCD was completely debrominated after 62 h of the contact. A notable time lag (∼12 h) from the onset of the adsorption to the debromination was observed, signifying the importance of the solid-phase mass transfer from the initially adsorbed AC particles to the reactive Al-AC interface. Overall, AC@mZVAl bm/NaCl synergizes the adsorptive properties of AC and the high reactivity of metallic Al, and enables a novel two-step adsorption and reductive degradation process for treating HBCD or likely other POPs. • A novel Al-carbon composite (AC@mZVAl bm/NaCl ) was prepared via NaCl-aided ball-milling. • AC@mZVAl bm/NaCl consists of a metallic Al core and a thin layer of carbon nanoparticles. • AC@mZVAl bm/NaCl rapidly adsorbed hexabromocyclododecane in water due to carbon coating. • AC@mZVAl bm/NaCl could debrominate most of the pre-sorbed hexabromocyclododecane. • The debromination was coupled with oxidation of the core Al into Al-(hydr)oxide.