材料科学
有机发光二极管
激发态
光电子学
系统间交叉
激子
单重态
电致发光
紫外线
光致发光
带隙
光化学
纳米技术
原子物理学
化学
物理
量子力学
图层(电子)
作者
Ziting Zhong,Xiangyu Zhu,Xianhui Wang,Yu Zheng,Sinuo Geng,Zhikuan Zhou,Xin Jiang Feng,Zujin Zhao,Hua Lü
标识
DOI:10.1002/adfm.202112969
摘要
Abstract Hybridized local and charge‐transfer (HLCT) excited‐state compounds that enable full exciton utilization through a reverse intersystem conversion (RISC) from a high‐lying triplet to a singlet state have attracted attention. Developing high‐performance ultraviolet (UV) and blue organic light‐emitting diodes (OLEDs) is challenging due to difficulties acquiring HLCT molecules with a large energy bandgap and a high photoluminescence. Herein, a new strategy for excellent‐performance UV to blue emitters based on high steric‐hindrance windmill‐type structure is proposed. These emitters exhibit good thermal, morphological, and electrochemical stabilities, as well as HLCT excited‐state characteristics. Results suggest that OLED using CTPPI efficiently emits UV light (396 nm, CIE x,y = 0.16, 0.04) with a maximum external quantum efficiency (EQE) of 7.9% and currently ranks third in UV OLEDs. The lights of these devices are well modulated from UV/deep‐blue to pure‐blue with EQEs greater than 5% by regulating the locally excited (LE) and charge‐transfer (CT) components. Experimental and theoretical investigations indicate that harvesting triplet excitons afford high electroluminescence efficiencies via HLCT excited states in the devices. This study provides an efficient strategy to achieve high‐performance UV and blue OLEDs and offers great flexibility for material design.
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