Cellulose-based photo-enhanced persistent room-temperature phosphorescent materials by space stacking effects

堆积 纤维素 材料科学 磷光 聚合物 极限抗拉强度 氢键 化学工程 复合材料 发光 光电子学 分子 化学 光学 有机化学 物理 工程类 荧光
作者
Maozhu Zeng,Li Tang,Yingchun Liu,Xuliang Lin,Xihong Zu,Yingxiao Mu,Liheng Chen,Yanping Huo,Yanlin Qin
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:446: 136935-136935 被引量:41
标识
DOI:10.1016/j.cej.2022.136935
摘要

• Cellulose-based materials with photo-enhanced pRTP properties is presented. • In-depth mechanism research with photo-enhanced pRTP properties of cellulose-based materials. • The excellent pRTP and mechanical properties in hot-pressed films are achieved. • Cellulose-based hot-pressed films are successfully employed for information encryption and flexible folding. Cellulose is environmentally friendly bio-based polymer with a large number of hydroxyl groups in its structure, which can easily form hydrogen bond networks. It has the potential to become excellent persistent room-temperature phosphorescence (pRTP) material through rational design. In this work, we reported a simple and universal strategy to obtain polymer film by connecting aromatic derivatives onto cellulose chains and drying them by hot press process. The emission color of pRTP from blue-green to red can be tuned by benzene or different polycyclic aromatic hydrocarbons as grafted groups, as well as the performance of photo-enhanced pRTP property. Notably, the lifetime of the best-performing film could be enhanced from 282.1 ms to 571.1 ms after irradiation for 1 min at room temperature. All the hot-pressed films were able to withstand Young's modulus up to nearly 18.0 GPa and tensile strength of around 80 MPa. The excellent luminescent and mechanical properties were derived from space stacking effects of the grafted groups and abundant intermolecular hydrogen bonding. These results will provide the effective design strategy for the modulation of smart-response pRTP materials, and expand the application range of cellulose-based materials.
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