热重分析
水溶液
吸附
纤维素
傅里叶变换红外光谱
打赌理论
纳米纤维
朗缪尔吸附模型
核化学
Zeta电位
吸附剂
静电纺丝
醋酸纤维素
扫描电子显微镜
化学工程
化学
材料科学
有机化学
纳米颗粒
复合材料
聚合物
纳米技术
工程类
作者
Muhammad Muqeet,Hammad Malik,Rasool Bux Mahar,Farooq Ahmed,Ick‐Soo Kim,Krista Carlson
标识
DOI:10.1021/acs.iecr.7b03739
摘要
In this study, the adsorption properties of cationized cellulose nanofibers (c-CNF) were examined for the removal of sulfate (SO42–) ions from aqueous solutions under diverse experimental conditions. Nanofiber mats were fabricated through electrospinning and cationized with 3-chloro-2-hydroxypropyl trimethylammonium chloride (CHTAC). The resultant c-CNF with an ammonium content of 0.134 mmol/g showed the maximum adsorption capacity of 24.5 mg of SO42– per gram of sorbent using a Langmuir isotherm model. A pseudo-second-order (PSO) kinetic model was fitted to the adsorption rate data, showing a higher adsorption rate of 0.0022 mg g–1 min–1. Scanning electron microscopy (SEM) micrographs revealed the average fiber diameter to be 280 ± 10 nm, and a BET surface area of 5.04 m2/g was obtained with a BET surface area and porosity analyzer. Fourier transform infrared (FTIR) spectroscopy confirmed the conversion of cellulose acetate (CA) to cellulose and its subsequent cationization. Furthermore, the consequences of cationization were evaluated by zeta potential measurements and thermogravimetric analysis (TGA).
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