化学
话筒
微量气体
分析化学(期刊)
弯曲分子几何
共振(粒子物理)
谐振器
信号(编程语言)
弯曲
吸收(声学)
光学
光电子学
原子物理学
声学
材料科学
物理
声压
复合材料
有机化学
色谱法
程序设计语言
计算机科学
作者
Bo Zhang,Jiachen Jiang,Xian Zhang,Yunjiang Jia,Xiao-Song Zhu,Yi-Wei Shi
出处
期刊:Analytical Chemistry
[American Chemical Society]
日期:2023-08-16
卷期号:95 (34): 12811-12818
被引量:12
标识
DOI:10.1021/acs.analchem.3c01784
摘要
A low-frequency flexible resonant photoacoustic (PA) gas sensor using an O-shaped multipass cell is demonstrated. The PA sensor employed a flexible gradually tapered leaky hollow core fiber (LHCF). The LHCF was bent to be an end-to-end structure to make full use of the incident light. Additionally, the two ends of the LHCF were put inside a single buffer chamber, yielding an equivalent H-type acoustic resonator. The geometric size was reduced thanks to the bending structure. The geometric length of the LHCF was 500 mm. A micro-electro-mechanical-systems electrical microphone was installed at the center of the resonant tube to detect the PA signal. The proposed PA gas sensor exhibited a first-order longitudinal resonance frequency of 408 Hz. Trace acetylene (C2H2) was used as the target gas. The minimum detectable limit was calculated to be 25.8 parts-per-billion (ppb) with an average time of 400 s, which was 1.93 times higher than that of a single-pass PA gas sensor. The normalized noise-equivalent absorption coefficient and the PA cell constant were calculated to be 9.6 × 10–9 W·cm–1·Hz–1/2 and 8295 Pa/W·cm–1, respectively. The PA gas sensor owns a low resonance frequency and can be used for detection of most of the polar gaseous molecules, especially suitable for gas molecules with a long V–T relation time, such as carbon monoxide and carbon dioxide.
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