Aromatic poly (amino acids) as an effective low-temperature demulsifier for treating crude oil-in-water emulsions

Amphiphilic aromatic poly (amino acids) polymers were designed as biodegradability demulsifiers with higher aromaticity, stronger polarity, and side chain-like combs. The effects of demulsifier dosage, structural characteristics and emulsion properties such as pH, salinity, and oil content on the demulsification efficiency were investigated. The results show that the poly (L-glutamic-benzyl ester)-block-poly (L-phenylalanine) (PBLG15-b-PPA15) as the demulsifier can remove more than 99.97% of the oil in a 5.0 wt% oil-in-water (O/W) emulsion at room temperature within 2 minutes. The poly (L-tyrosine)-block-poly (L-phenylalanine) (PTyr15-b-PPA15) with environmental durability demonstrates high effectiveness, universality, and demulsification speed. It achieves a remarkable demulsification efficiency of up to 99.99% for a 20.0 wt% O/W emulsion at room temperature. The demulsification mechanism indicates that demulsifiers have sufficient interfacial activity can quickly migrate to the oil-water interface after being added to the emulsions. Additionally, when demulsifiers are present in a continuous phase in the molecular form, their "teeth" side chains are beneficial for increasing coalescence and flocculation capacities. Furthermore, according to the Density Functional Theory (DFT) calculations, enhancing the intermolecular interactions between demulsifiers and the primary native surfactants that form an oil-water interfacial film is a more efficient approach to reducing demulsification temperature and improving demulsification efficiency and rate. The complicated emulsions and oily wastewater, which are produced from industrial processes such as coal, material engineering, and petroleum recovery, have adversely affected aquatic resources. Thus, efficient and rapid demulsification and separation of various complex emulsions can significantly reduce production costs and environmental pollution. In this work, we offered a new avenue for the development of low-temperature demulsifiers by improving the aromatic content and polarity of the demulsifiers. More importantly, the synthesized aromatic poly (amino acid) demulsifier is suitable for a wide range of O/W emulsions and oily wastewater and has efficient and fast demulsification at room temperature.