阴极
煅烧
降级(电信)
碳纤维
化学工程
纳米颗粒
材料科学
电极
阳极
热液循环
制作
纳米技术
化学
催化作用
复合数
有机化学
复合材料
医学
电信
替代医学
物理化学
病理
计算机科学
工程类
作者
Shuang Pan,Chang Liu,Yanchao Li,Can Wang,Xiaoya Cui,Ning Liu,Cong Zhang,Israel Hakizimana,Xin Zhao,Wei‐Di Liu,Yanan Chen
标识
DOI:10.1016/j.electacta.2022.141262
摘要
Heterogeneous electro-Fenton (EF) is a promising advanced oxidation process for refractory wastewater treatment. However, typical calcination or hydrothermal method for heterogeneous EF cathode fabrication is time-consuming, energy-consuming, or harmful to the environment. High-temperature shock (HTS) technique is a novel and rapid material synthesis method with the advantages of low-cost, eco-friendly. In this study, the electrodes named Fe2O3@C/carbon cloth (Fe2O3@C/CC), were synthesized by HTS for the first time within an extremely short time (∼5 s). The Fe2O3 nanoparticles with an average diameter of 61.90 ± 15.09 nm are uniformly dispersed on carbon cloth (CC) with the confinement and protection of the carbon layers. The as-prepared Fe2O3@C/CC cathode exhibited excellent electrocatalytic properties in the EF system. The removal efficiency of methylisothiazolinone (MIT) could reach 90.60 ± 1.70% in 40 min at a low current density of 1.11 mA cm−2 under the oxidation of the hydroxyl radical. In addition, the degradation pathways of MIT were further studied. According to the results of theoretical calculation, the –S–N– bond is the primary active site attacked during MIT degradation process. Therefore, heterocyclic loop opening is the main pathway of MIT degradation. HTS is an ultrafast and convenient potential technique compared with other cathode synthesis methods.
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