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Is Salt Melting When It Dissolves in Water?

溶解 灵活性(工程) 化学 确定性 盐(化学) 化学物理 数学 认识论 有机化学 哲学 统计
作者
Alan M Goodwin
出处
期刊:Journal of Chemical Education [American Chemical Society]
卷期号:79 (3): 393-393 被引量:20
标识
DOI:10.1021/ed079p393
摘要

This paper explores the terms melting and dissolving as applied to a variety of pure substances and mixtures, including water, salt solutions, and alloys. Even though the two terms are usually strongly differentiated in elementary science teaching, it is concluded that the two processes are essentially the same as soon as the ideas are extended to systems containing more than one component. By definition, the extension to two components has already been done when solutions are considered. Both melting and dissolving involve transition between the solid and liquid states and are controlled by analogous thermodynamic and kinetic principles. It is suggested that very strong differentiation between the terms is unnecessary and potentially damaging. In elementary science learning, signaling that "salt melting into water is a totally wrong concept" may erect a barrier to subsequent chemistry learning.There are many parallels to this dilemma in making strong differentiation between classifications throughout the learning and teaching of chemistry. Other examples include solute and solvent, and physical and chemical changes. Seeking an appropriate balance between certainty and flexibility seems to be important for current learning in chemistry and, at the same time, facilitating more sophisticated learning in the future. A feature of this paper is the continuing development of the author's understanding of melting and dissolving, a process that is clearly not yet complete.
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