碳阳离子
化学
烯烃
分子内力
庚烯
戒指(化学)
辛烯
苯
立体化学
芳香性
双环分子
药物化学
有机化学
分子
乙烯
催化作用
作者
Thomas A. Spencer,Janeta Popovici-Müller,Bobbijo van Beusichem,Celeste Viscardi MacMillan,Carolee Lavey,Jessica M. Sin,R. Ditchfield
出处
期刊:Tetrahedron
[Elsevier]
日期:2010-06-01
卷期号:66 (25): 4441-4451
被引量:10
标识
DOI:10.1016/j.tet.2010.04.029
摘要
Toward the goal of gaining further insight into carbocation–π interactions, bridged-ring aromatic alkene model systems are being investigated in which one isomer will permit π complexation of an intramolecular tertiary carbocation with a benzene ring, but the other isomer will not. The syntheses of three sets of such isomers, having, respectively, benzobicyclo[3.2.1]octene, benzobicyclo[2.2.1]heptene, and benzobicyclo[4.2.1]nonene structures, are described.
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