Gel‐Based Electrolytes for Organic Electrochemical Transistors: Mechanisms, Applications, and Perspectives

Abstract Organic electrochemical transistors (OECTs) have emerged as the core component of specialized bioelectronic technologies due to their high signal amplification capability, low operating voltage (<1 V), and biocompatibility. Under a gate bias, OECTs modulate device operation via ionic drift between the electrolyte and the channel. Compared to common electrolytes with a fluid nature (including salt aqueous solutions and ion liquids), gel electrolytes, with an intriguing structure consisting of a physically and/or chemically crosslinked polymer network where the interstitial spaces between polymers are filled with liquid electrolytes or mobile ion species, are promising candidates for quasi‐solid electrolytes. Due to relatively high ionic conductivity, the potential for large‐scale integration, and the capability to suppress channel swelling, gel electrolytes have been a research highlight in OECTs in recent years. This review summarizes recent progress on OECTs with gel electrolytes that demonstrate good mechanical as well as physical and chemical stabilities. Moreover, various components in forming gel electrolytes, including different mobile liquid phases and polymer components, are introduced. Furthermore, applications of these OECTs in the areas of sensors, neuromorphics, and organic circuits, are discussed. Last, future perspectives of OECTs based on gel electrolytes are discussed along with possible solutions for existing challenges.