Guanidine Carbonate Modified TiO2/Perovskite Interface for Efficient and Stable Planar Perovskite Solar Cells

The rational design and modification of the buried interface are essential and challenging for high-performance perovskite solar cells (PSCs). TiO2 is a simple and readily available electron transport layer material, but its surface defects and poor interfacial contact with perovskite layers hinder its widespread application. Here, we propose an effective TiO2/perovskite interface modification strategy by introducing simple guanidine carbonate (GuaCO3) onto the surface of TiO2. Guanidine carbonate can improve the interfacial contact between TiO2 and perovskite, reduce non-radiative recombination, and enhance carrier extraction. Moreover, the PbI2 film grown on the TiO2/GuaCO3 substrate tended to become porous during the preparation of perovskite films by the traditional two-step method, which facilitated the complete reaction of organic ammonium salts with PbI2 and promoted the growth of high-quality perovskite films. The experimental results indicate that GuaCO3 can passivate the interfacial defects of TiO2/perovskite, as well as reduce the accumulation of interfacial charges. The device modified with GuaCO3 achieved a power conversion efficiency (PCE) of 23.39%, which is significantly higher than that of the control device (21.73%). After storage in an ambient environment at room temperature for 600 hours, the unencapsulated device modified with GuaCO3 retained 78% of its initial efficiency, while the control device retained only 57% of its initial efficiency. These results indicate that interfacial modification with GuaCO3 is an effective strategy for improving the performance of PSCs.