Improving the interfacial adhesion between recycled carbon fibres and polyphenylene sulphide by bio-inspired dopamine for advanced composites manufacturing

Polyphenylene sulphide composites with recycled carbon fibres are of high interest due to their promising mechanical properties. Poor interface adhesion between recycled carbon fibre and thermoplastic matrix, however, remains a major problem in composite manufacturing. Herein, a novel one-step method using bio-inspired copolymerisation of dopamine to graft silica nanoparticles onto the carbon fibre surface is reported. Comprehensive investigations were conducted to fabricate the treated carbon fibre and characterise the modified samples by analysing the surface morphology and functional groups. The experimental results reveal that the network of bio-inspired adhesive polydopamine and nanoparticles adhering to the fibres can improve inter-laminar shear strength by 28.4% in the resulting composites. In addition, dynamical mechanical analysis results prove that the interfacial bonding at the fibre/matrix interface provides good resistance to thermal cycling. This novel approach introduces the functional groups on the recycled carbon fibre surface, leading to an improvement of surface energy and wettability between the carbon fibres and polyphenylene sulphide matrix and constitutes a robust and green approach to the manufacturing of advanced composites.