聚磷酸铵
热重分析
材料科学
阻燃剂
聚乙二醇
差示扫描量热法
复合材料
PEG比率
木粉
复合数
化学工程
物理
财务
工程类
经济
热力学
作者
Ke Wang,Chuan Liu,Wenxi Xie,Yihan Ke,Xiaoyong You,Binghao Jing,Yongqian Shi
出处
期刊:Molecules
[MDPI AG]
日期:2023-04-14
卷期号:28 (8): 3464-3464
标识
DOI:10.3390/molecules28083464
摘要
With the depletion of fossil fuel energy and both the slow development and low utilization rate of new eco-friendly energy, finding new ways to efficiently store energy has become a research hotspot. Presently, polyethylene glycol (PEG) is an excellent heat storage material, but it is a typical solid-liquid phase change material (PCM) with a risk of leakage during phase transition. A combination of wood flour (WF) and PEG can effectively eliminate the risk of leakage after the melting of PEG. However, WF and PEG are both flammable materials, which impedes their application. Therefore, it is of great significance to expand their application by forming composites from among PEG, supporting mediums, and flame-retardant additives. This will improve both their flame retardancy and phase change energy storage performance, and will also lead to the preparation of excellent flame-retardant phase change composite materials with solid-solid phase change characteristics. To address this issue, ammonium polyphosphate (APP), organic modified montmorillonite (OMMT), and WF were blended into PEG in specific proportions to prepare a series of PEG/WF-based composites. Both thermal cycling tests and thermogravimetric analysis results demonstrated that the as-prepared composites had good thermal reliability and chemical stability. In addition, during differential scanning calorimetry tests, the PEG/WF/8.0APP@2.0OMMT composite presented the highest melting latent heat (176.6 J/g), and its enthalpy efficiency reached more than 98.3%. The PEG/WF/8.0APP@2.0OMMT composite also exhibited superior thermal insulation performance when compared to the pure PEG/WF composite. Furthermore, the PEG/WF/8.0APP@2.0OMMT composite exhibited a significant 50% reduction in peak heat release rate as a result of the synergistic effect between OMMT and APP in the gas and condensed phases. This work offers a useful strategy for the fabrication of multifunctional phase-change material, which is expected to broaden its industrial applications.
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