Effects of Electron–Phonon Coupling and Spin–Spin Coupling on the Photoluminescence of Low-Dimensional Metal Halides

Low-dimensional metal halides (LDMHs), as a derivative of three-dimensional lead halide perovskites, have attracted much attention because of their unique crystal structures and fascinating photonic properties. The simple synthesis and rich photonic properties of LDMHs make them striking candidates for the development of lighting, photodetectors, biological imaging, etc. Although many novel LDMHs have been achieved with strong electron-phonon coupling related to their self-trapped excitons (STEs) and excellent optical responses, transition-metal halides or doped halides have not been covered in regard to their rich spin characteristics. In this Perspective, we aim to deeply understand the role of electron-phonon coupling and STEs with magnetic coupling effects in regulating the optical properties of LDMHs and try to provide a novel way or a series of novel systems for the realization of next-generation high-performance luminescent materials with spin-coupling-involved photonics. Finally, an outlook toward potential challenges and applications of such ionic semiconducting LDMHs is also presented.