Polymer-Protected Bimetallic Clusters. Preparation and Application to Catalysis

Colloidal dispersions of polymer-protected Pd/Pt and Pd/Au bimetallic clusters were prepared by reduction of an alcoholic solution of PdCl2 and H2PtCl6 or HAuCl4 in the presence of poly(N-vinyl-2-pyrrolidone). The reduction can be carried out by refluxing in alcohol or by irradiation with visible light. The dispersions of the bimetallic clusters obtained are stable for months at room temperature and have from dark brown to brownish red color. Transmission electron micrographs show that the bimetallic clusters are composed of well-dispersed ultrafine particles of uniform size, about 1.5 nm for Pd-Pd and 3.4 nm for Pd-Au in diameter. The catalytic activity of the bimetallic clusters depends on the metal composition. In the case of the partial hydrogenation of 1, 3-cyclooctadiene, the activity went through a maximum when the alloy composition reached about 80% Pd and 20% Pt, or 60% Pd and 40% Au.