动力学分辨率
化学
动能
立体化学
分辨率(逻辑)
有机化学
对映选择合成
催化作用
物理
计算机科学
量子力学
人工智能
作者
Simon Jones,Dimitrios Selitsianos
标识
DOI:10.1016/j.tetasy.2005.08.025
摘要
Abstract A number of chiral N-phosphoryl oxazolidinones have been prepared and evaluated as asymmetric phosphoryl transfer agents with the magnesium alkoxide of 1-phenyl ethanol. The reaction proceeded with little stereoselection, which was shown to be a consequence of the reaction mechanism that occurs with inversion of configuration at phosphorus consistent with in-line attack opposite the leaving group.
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