材料科学
结晶度
碳纳米管
结晶
傅里叶变换红外光谱
差示扫描量热法
复合材料
动态力学分析
氟化物
相(物质)
复合数
化学工程
聚合物
有机化学
无机化学
化学
物理
工程类
热力学
作者
Linghao He,Qun Xu,Chengwu Hua,Rui Song
摘要
Composites were prepared by solution blending poly(vinylidene fluoride) (PVDF) and multi-walled carbon nanotubes (MWNTs). Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) results showed that the crystalline structure of PVDF was changed by the addition of MWNTs and a MWNTs-induced crystal transformation from α-phase to β-phase of PVDF was confirmed. With differential scanning calorimeter (DSC) and dynamic mechanic thermal analysis (DMA) techniques, thermal and mechanical properties of the composite films were examined. As the DSC results showed, addition of MWNTs would lead to the increased cooling crystallization temperature (Tc), implying that MWNTs nanoparticles could act as nucleating agents, which is further proved with the help of polarized optical microphotographs. On the other hand, the decreasing of Dd (degree of crystallinity) implied that the MWNTs networks can confine the crystallization of PVDF. Through the curve analysis of the dynamic mechanical measurements, it was found that the storage modulus (E′) is significantly enhanced, revealing that a strong interaction should exist between PVDF and MWNTs. POLYM. COMPOS., 2010. © 2009 Society of Plastics Engineers
科研通智能强力驱动
Strongly Powered by AbleSci AI