阳极
材料科学
电解质
箔法
化学工程
锂(药物)
复合数
电化学
电极
溅射沉积
锂离子电池
扩散
溅射
复合材料
电池(电)
薄膜
纳米技术
化学
物理化学
功率(物理)
内分泌学
工程类
物理
热力学
量子力学
医学
作者
Menglu Sun,Jie Wu,Ping Lü,Zhonghua Zhang,Yifan Zhang,Dejun Li
标识
DOI:10.1016/j.jallcom.2021.162075
摘要
In this paper, a sphere-like MoS2 and porous TiO2 composite film was prepared on Ti foil by plasma electrolytic oxidation and magnetron sputtering methods. The prepared film was assembled as a binder-free anode in the lithium-ion battery and a Li foil served as the counter electrode. The specific capacity and cycling stability of the electrode were evaluated, together with the cyclic voltammograms and electrochemical impedance spectra. The TiO2/MoS2 composite film anode combined the advantages of TiO2 with high structural stability and MoS2 with high theoretical capacity. The electrochemical performance exhibited a specific capacity above 400 mAh g−1 at the current density of 100 µA cm−2, which was much higher than that of the TiO2 anode. Besides, after cycling under a high current density of 1000 μA cm−2, the capacity came back to 91% of the initial capacity, showing a good rate capability. The porous TiO2 prepared by plasma electrolytic oxidation can provide a significant number of internal channels for the Li+ diffusion, resulting in a high porosity of 33.5–41.6%, and a high Li+ diffusion coefficient of 3.12 × 10−14–6.67 × 10−14 cm2/s, which was beneficial for the enhanced electrochemical performance.
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