并五苯
双极扩散
材料科学
有机场效应晶体管
轨道能级差
光电子学
有机半导体
晶体管
电极
场效应晶体管
纳米技术
图层(电子)
薄膜晶体管
电子
电气工程
化学
分子
有机化学
工程类
物理化学
电压
物理
量子力学
作者
Miho Higashinakaya,Takashi Nagase,Hirotake Abe,Reitaro Hattori,Shion Tazuhara,Takashi Kobayashi,Hiroyoshi Naito
摘要
The development of nonvolatile organic field-effect transistor (OFET) memories with a satisfactory solution processability is highly desirable to fabricate the data storage media for flexible and printed electronic devices. In this study, we fabricate top-gate/bottom-contact OFET memories having an organic floating-gate structure by a spin-coating process and investigate their memory characteristics. An ambipolar polymer semiconductor of poly(N-alkyldiketopyrrolo-pyrrole-dithienylthieno[3,2-b]thiophene) (DPP-DTT) was used to fabricate an organic semiconductor layer, on which an organic composite of polystyrene and 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-pentacene) was deposited to form an organic floating-gate structure through vertical phase separation. The existence of a deep lowest unoccupied molecular orbital (LUMO) level and the excellent electron transport property of the DPP-DTT enables the injection of electrons from the Au source-drain electrodes to the DPP-DTT semiconductor layer and the storage of electrons in the LUMO level of the TIPS-pentacene floating gates by programming under dark conditions. A high work function metal oxide layer of MoO3 was inserted at the Al gate electrode/CYTOP gate insulator interface to tune the energy level difference between the Au source-drain and Al gate electrodes. The DPP-DTT FET memories with MoO3/Al gate electrodes exhibit satisfactory retention characteristics and, because of the ambipolar trapping characteristics, allow the storing of holes in the highest occupied molecular orbital level of the TIPS-pentacene floating gates in the erasing process. Furthermore, the molecular floating-gate OFET memories exhibit a high storage capacity for multi-level data, and four state levels can be recorded with stable retention characteristics.
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