Comparative study on front emitter and rear emitter n-type silicon heterojunction solar cells: The role of folded electrical fields

共发射极 量子效率 光电子学 材料科学 能量转换效率 开路电压 基质(水族馆) 非晶硅 电流密度 晶体硅 短路 兴奋剂 太阳能电池 电压 电气工程 物理 工程类 地质学 海洋学 量子力学
作者
Sen Li,Zhaojun Tang,Junming Xue,Jiao Gao,Zhifeng Shi,Xinjian Li
出处
期刊:Vacuum [Elsevier BV]
卷期号:149: 313-318 被引量:6
标识
DOI:10.1016/j.vacuum.2017.12.041
摘要

Here, we presented a comparative investigation on the front and rear emitter n-type silicon heterojunction (SHJ) solar cells. The cell performances showed that the rear emitter SHJ solar cell featured higher open-circuit voltage (Voc), fill factor (FF) and conversion efficiency (Eff.), but suffering from a lower short-circuit current density (Jsc). The poor Jsc agreed well with the external quantum efficiency (EQE) results, that rear emitter SHJ had a inferior EQE than the front emitter ones, although the thinner a-Si:H(n+) layer had a better optical transmittance than that of a-Si:H(p) layer. Then, by adjusting the thickness of two sides intrinsic hydrogenated amorphous silicon (a-Si:H(i)) layers in the rear emitter SHJ solar cells, the Eff.s were further improved. It was believed that the folded electrical fields formed by ITO, doped a-Si:H layers, and n-type crystalline silicon (c-Si(n)) substrate played a great role on the cell performances. Consequently, by combining the optimized thickness of doped and intrinsic a-Si:H layers, for the rear emitter SHJ solar cells, a full-area certified Eff. of 21.71% on large area of 238.9 cm2 substrate was obtained, with a Voc of 0.731 V, Jsc of 37.46 mA/cm2, and FF of 0.793. Note that, the 21.71% full-area conversion efficiency relates to an aperture-area conversion efficiency of 22.57%.
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