膜
电导率
化学
磷酸
离子液体
高分子化学
磷酸盐
质子
咪唑
电解质
离子电导率
离子键合
离子
有机化学
电极
物理化学
催化作用
物理
量子力学
生物化学
作者
Xu Wang,Shuang Wang,Chang Liu,Jinsheng Li,Fengxiang Li,Xue Tian,Hao Chen,Tiejun Mao,Jingmei Xu,Zhe Wang
标识
DOI:10.1016/j.electacta.2018.06.197
摘要
Polybenzimidazole/ionic liquid (IL) composite membranes with cage-like cross-linked structure were prepared based on polybenzimidazole containing hydroxyl groups (PBIOH30), 3-(triethoxysilyl) propyl isocyanate (IPTS) and 1-butyl-3-methylimidazolium dihydrogen phosphate (BMI-DHPH). The basic characteristic of imidazole rings in IL enhanced the phosphoric acid (PA) doping ability of the obtained cPBI-IL X membranes, thus, the proton conductivity of which was elevated. The cage-like cross-linked structure was formed under acidic conditions, and such structure can not only strengthen the mechanical properties of cPBI-IL X membranes but also prevent the leakage of the IL to some extent. The IL retention ability of cPBI-IL 10 was significantly improved, the residual weight percentage of IL was 71.6 wt%, while that of PBI-IL 10 membrane without cage-like cross-linked structure was only 2 wt%. The membrane with 8 wt% IL content exhibited the highest proton conductivity of 0.133 S cm−1 at 160 °C.
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