吸附
化学
乙醚
洗脱
解吸
聚合
盐(化学)
氧气
卤水
聚合物
色谱法
无机化学
有机化学
作者
Zihao Xu,Meng Rong,Shan Ni,Qiyu Meng,Liyan Chen,Huizhou Liu,Liangrong Yang
标识
DOI:10.1016/j.seppur.2021.120285
摘要
Hypercrosslinked polymers (HCPs) with synergistic effect of ether oxygen and phenolic hydroxyl groups was designed and fabricated for Cs+ isolation in the salt lake system. The separation factors (S.F.)(Cs+/K+) of the adsorbents were significantly increased through regulating the content of the ether oxygen group in the frameworks. The S.F. of PO-HCPs-6 was increased by nearly 5 times to an ultra-high value (S.F. = 57) compared with the Cs+ adsorbents reported in the literature. Moreover, the mild and sufficient polymerization process endowed PO-HCPs-6 with an extremely fast kinetic adsorption rate. PO-HCPs-6 could quickly reach 90% of the equilibrium adsorption capacity in just 1 min. Finally, after 5 times adsorption–desorption experiments, the remarkable elution rate (>92%) and reusability adsorption capacity (>91%) of PO-HCPs-6 proved it has inspiring application potential for the Cs+ isolation in the salt lake brine system.
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