钙钛矿(结构)
结晶度
材料科学
太阳能电池
钙钛矿太阳能电池
光伏系统
非阻塞I/O
降级(电信)
热稳定性
工作(物理)
理论(学习稳定性)
化学工程
光电子学
化学
计算机科学
复合材料
物理
电气工程
热力学
有机化学
催化作用
工程类
机器学习
电信
作者
Aimé Magloire Ntouga Abena,Ariel Teyou Ngoupo,François Xavier Abomo Abega,J.M.B. Ndjaka
标识
DOI:10.1016/j.cjph.2021.12.024
摘要
Among the major problems hindering the performance and commercialisation of conventional MAPbI3 solar cells are thermal instability, degradation, defects and the high cost of Spiro-OMeTAD HTL. However, the hybrid or mixed organic cation perovskite (MA1-xFAxPbI3) has good crystallinity which can reduce defects and increase the charge carrier lifetime. The aim of this work is to find, by numerical simulation using SCAPS-1D software, a better substitute for organic Spiro-OMeTAD HTL in order to solve the problems caused by it. First, we validated our solar cell structures by a comparative study of the J-V characteristics of the experiment and the simulation. Secondly, we conducted a numerical simulation study of a number of inorganic HTLs (NiO, CuI, CuSCN, MoO3, and Cu2O) that replace Spiro-OMeTAD in the hybrid organic cation perovskite cell structure. Based on the study of the performance and stability of these different HTLs, we obtain Cu2O HTL as the best candidate to substitute the organic Spiro-OMeTAD HTL. The MA1-xFAxPbI3-based solar cell with Cu2O as inorganic HTL shows a very good stability (TC = -0.0014%/°C) and better performance with an efficiency of 26.67%. This work contributes to a better knowledge on the numerical optimization of perovskite-based solar cells.
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