Bio-polyols based waterborne polyurethane coatings reinforced with chitosan-modified ZnO nanoparticles

The development of environmentally friendly waterborne polyurethane (WPU) coatings from bio-based polyols has received much attention due to increasing environmental concern and the depletion of petroleum resources. In this study, the WPU coatings derived from castor oil and soy polyol were modified by chain extender [bis(2-hydroxyethyl)amino]-methyl-phosphonic acid dimethyl ester. The effect of chitosan-modified ZnO (CS-ZnO) nanoparticles content on the properties of WPU/CS-ZnO coatings and their films were systematically investigated. The results indicated that WPU/CS-ZnO coatings displayed excellent storage stability and the particle sizes firstly decreased and then increased with CS-ZnO loading. CS-ZnO could improve tensile strength and Young's modulus but reduce the optical transparency of WPU/CS-ZnO films. CS-ZnO has a prominent reinforcement effect on the WPU/CS-ZnO matrix. With the addition of 2 wt% CS-ZnO, the tensile strength and Young's modulus of the WPU/CS-ZnO2 film reached 13.4 and 112.1 MPa, 1.68 and 2.6 times over neat WPU film, respectively. TGA results showed that the thermal stability of WPU/CS-ZnO films improved with increased CS-ZnO content. Furthermore, the WPU/CS-ZnO films' wettability decreased with the introduction of CS-ZnO. This work provides a simple and efficient strategy for preparing environmentally friendly bio-based WPU coatings, which are promising for application in the surface coating industry.