Magnesium isotope geochemistry of the carbonate-silicate system in subduction zones

Abstract The lighter magnesium (Mg) isotopic signatures observed in intraplate basalts are commonly thought to result from deep carbonate recycling, provided that the sharp difference in Mg isotopic composition between surface carbonates and the normal mantle is preserved during plate subduction. However, deep subduction of carbonates and silicates could potentially fractionate Mg isotopes and change their chemical compositions. Subducting silicate rocks that experience metamorphic dehydration lose a small amount of Mg, and preserve the original Mg isotopic signature of their protoliths. When the dehydrated fluids dissolve carbonate minerals, they may evolve into lighter Mg isotopic compositions. The solubility of carbonate minerals in fluids decreases in the order of calcite, aragonite, dolomite, magnesite and siderite, leading to selective and partial dissolution of carbonate minerals along the subduction path. At the island arc depth (70–120 km), the metamorphic fluid dissolves mainly Mg-poor calcites, and thus the fluid has difficulty modifying the Mg isotopic system of the mantle wedge and associated arc basalts. At the greater depth of the back arc system or continental margin (>150 km), the supercritical fluid can dissolve Mg-rich carbonate minerals, and its interaction with the mantle wedge could significantly imprint the light Mg isotopic signature onto the mantle rocks and derivatives. Meanwhile, the carbonate and silicate remaining within the subducting slab could experience elemental and isotopic exchange, during which the silicate can obtain a light Mg isotopic signature and high CaO/Al2O3, whereas the carbonates, particularly the Ca-rich limestone, shift Mg isotopes and MgO contents towards higher values. If this isotopic and elemental exchange event occurs widely during crustal subduction, subducted Ca-rich carbonates can partially transform into being Mg-rich, and a portion of recycled silicates (e.g. carbonated eclogites) can have light Mg isotopic composition alongside carbonates. Both serve as the low-δ26Mg endmember recycled back into the deep mantle, but the latter is not related to deep carbonate recycling. Therefore, it is important to determine whether the light Mg isotopic signatures observed in intraplate basalts are linked to deep carbonate recycling, or alternatively, recycling of carbonated eclogites.