催化作用
沸石
甲醇
酸强度
结晶
化学
选择性
Crystal(编程语言)
化学工程
氟化物
无机化学
材料科学
有机化学
计算机科学
工程类
程序设计语言
作者
Lina Zhang,Yang Liu,Runze Liu,Xueguang Shao,Weili Dai,Guangjun Wu,Naijia Guan,Zhihui Guo,Weiping Zhu,Landong Li
标识
DOI:10.1016/j.micromeso.2022.111767
摘要
Constructing plate-like zeolites with the controllable acidity represents an efficient strategy to promote their catalytic performance in methanol-to-olefins conversion. Herein, the plate-like H[Al/Ga]MFI zeolites with the similar crystal morphology but controllable acidity have been prepared via a fluoride-assisted low-temperature crystallization approach. The acidic properties of the plate-like zeolites are determined by NH3-TPD and probe-assisted 1H and 31P MAS NMR spectroscopy. The impact of acidity including the strength and density of the plate-like H[Al/Ga]MFI on the dual-cycle mechanism and the corresponding catalytic performance in the methanol-to-propylene conversion is subsequently confirmed. Reducing the acid strength and density can efficiently suppress the aromatic-based cycle, and thus hinder the accumulation of the polycyclic aromatics. The plate-like H[Ga]MFI zeolites with weak acid strength and most suitable acid density can well balance the dual-cycle mechanism, thereby achieving high propylene selectivity and long catalyst lifetime simultaneously.
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