偶氮苯
异构化
上临界溶液温度
材料科学
氢键
光化学
色谱中的热响应聚合物
共价键
偶氮化合物
光异构化
聚合物
高分子化学
化学
离子键合
分子
相(物质)
低临界溶液温度
有机化学
共聚物
催化作用
离子
反相色谱法
作者
Caihong Wang,Peiqi Li,Shiguo Zhang,Guoqiang Zhang,Shuai Tan,Yong Wu,Masayoshi Watanabe
出处
期刊:Macromolecules
[American Chemical Society]
日期:2020-06-03
卷期号:53 (12): 4901-4907
被引量:21
标识
DOI:10.1021/acs.macromol.0c00652
摘要
Photomoieties are generally covalently attached to thermoresponsive polymers to prepare photo/thermoresponsive materials, but the bonded thermo- and photomoieties prevent us from obtaining insights into the effect of the individual response. To clarify the synergetic effect, azobenzene molecules, structurally free from poly(N-isopropylacrylamide) (PNIPAm), are utilized as photoresponsive triggers to tune upper critical solution temperature (UCST) behaviors of PNIPAm in ionic liquids (ILs). PNIPAm in an IL becomes soluble upon trans-to-cis isomerization of azobenzene under UV irradiation and aggregates again under visible light illumination. It is revealed that cis-azobenzene promotes the interaction between PNIPAm and anions but suppresses hydrogen bonding between PNIPAm chains, contributing to lower clouding temperatures under UV irradiation. Furthermore, the light-switchable macroscopic response of PNIPAm/azobenzene/IL is first exploited for an application of photoinduced reversible adhesives. This work sheds light on the intrinsic relationship between the phase transition of PNIPAm and isomerization of azobenzene in multicomponent systems.
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