色素敏化染料
介电谱
电解质
材料科学
化学工程
能量转换效率
蛋清
电导率
化学
电化学
电极
有机化学
光电子学
工程类
物理化学
作者
Sarika Kelkar,Komal Pandey,Shruti Agarkar,Nidhi Saikhedkar,Mukta Tathavadekar,Ishita Agrawal,G. V. N. Rathna,Satishchandra Ogale
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2014-11-18
卷期号:2 (12): 2707-2714
被引量:23
摘要
In this report, we demonstrated an interesting application of a bioderived material for the dye sensitized solar cells (DSSCs). Egg white, the clear liquid in a hen’s egg, which possesses a remarkable gelling/cross-linking ability, was applied in the form of a gel electrolyte in a DSSC architecture to enhance its durability. A hybrid gel composed of poly(acrylic acid), polyaniline and egg albumen was synthesized, and the cell efficiency, stability and durability of the corresponding DSSC device were studied in detail. The dye sensitized solar cell with the egg albumen based electrolyte demonstrated a conversion energy efficiency of 4.6%. Further, a chemically modified egg albumen with ethylenediaminetetraacetic dianhydride showed improved cross-linking, microstructural and conductivity properties of the gel, and yielded a remarkable 5.75% conversion efficiency. Electrochemical impedance spectroscopy data showed favorable characteristics for charge transport through the modified gel and supported the efficiency observations very well.
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