双金属片
催化作用
选择性
氧化物
金属
无机化学
化学
材料科学
化学工程
有机化学
冶金
工程类
作者
Shyam Kattel,Weiting Yu,Xiaofang Yang,Binhang Yan,Yanqiang Huang,Weiming Wan,Ping Liu,Jingguang G. Chen
标识
DOI:10.1002/anie.201601661
摘要
By simply changing the oxide support, the selectivity of a metal-oxide catalysts can be tuned. For the CO2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO2 , ZrO2 , and TiO2 ), replacing a TiO2 support by CeO2 or ZrO2 selectively strengthens the binding of C,O-bound and O-bound species at the PtCo-oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal-oxide catalysts can be fine-tuned.
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