过电位
催化作用
材料科学
箔法
化学工程
热解
晶界
电化学
多孔性
纳米技术
法拉第效率
无机化学
冶金
复合材料
电极
微观结构
有机化学
工程类
物理化学
化学
作者
Yuhan Hu,Hongpeng Wu,Yao‐Yue Yang,Xianghong Lin,Hailian Cheng,Rui Zhang,Xiaole Jiang,Jing Wang
标识
DOI:10.1007/s11051-021-05271-9
摘要
Electrocatalytic CO2 reduction reaction has been considered as a promising route to realize carbon cyclic utilization and renewable energy storage. Recently, Zn-based catalysts have attracted much attention due to their earth-abundant reserve and low cost, which can meet the demand for commercial applications at a large scale. Herein, ZnO catalyst (ZIF-8-D-ZnO) was synthesized by pyrolysis of ZIF-8 precursor for electrocatalytic reduction of CO2. The ZIF-8-D-ZnO catalyst exhibits an excellent catalytic activity for CO production than rod-like ZnO and Zn foil catalysts, with faradaic efficiency of 86.7 % and geometric current density of 16.1 mA cm−2 at −1.2 V (vs. RHE). Moreover, the overpotential over ZIF-8-D-ZnO is much lower than that of analogous catalysts. The results suggest that the grain boundaries within the porous structure facilitate CO2 electroreduction over ZIF-8-D-ZnO due to the introduction of new catalytically active sites. This work provides experimental evidence for the design of efficient Zn-based materials for CO2 electrocatalytic reduction. ZIF-8-D-ZnO catalyst with porous structure and grain boundaries exhibits much higher CO faradaic efficiency and current density than ZnO-R and Zn foil catalysts.
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