催化作用
双酚A
化学
吸附
煅烧
生物炭
纳米复合材料
过硫酸盐
硫酸盐
过氧二硫酸盐
共沉淀
降级(电信)
铜
激进的
光化学
光催化
腐植酸
纳米颗粒
无机化学
傅里叶变换红外光谱
废水
水处理
化学工程
热解
有机化学
环氧树脂
工程类
电信
计算机科学
作者
Jianyuan Zhen,Shuoshuo Zhang,Xuming Zhuang,Shakeel Ahmad,Tae-Ho Lee,Hongyu Si,Chengbo Cao,Shou-Qing Ni
标识
DOI:10.1016/j.jwpe.2021.102078
摘要
Magnetic CuO-Fe3O4-Biochar (CuO-Fe3O4-BC) nanoparticles were successfully synthesized by two steps of coprecipitation and calcination and were characterized as a heterogeneous catalyst to activate peroxymonosulfate for bisphenol A (BPA) degradation. The reaction process and mechanism of heterogeneous catalyst adsorption and synergistic catalytic oxidation for the removal of BPA in CuO-Fe3O4-BC/PMS system were extensively evaluated in view of the practical applications. Results indicated that the addition of CuO achieved a high removal efficiency of BPA in a wide pH range. BPA removal efficiency reached 100 % in 30 min by using 2.0 g/L CuO-Fe3O4-BC and 5 mM PMS at a pH of 9.0, and SO4− played an essential role in the degradation process. The synergistic effect of copper ions and iron ions accelerated the circulation of Fe (II)/Fe (III) and Cu (I)/Cu (II), which improved the electron transfer on the catalyst surface and increased the free radical generation rate. CuO, Fe3O4 and BC achieved a synergistic effect between adsorption and catalysis. The stability and reusability of CuO-Fe3O4-BC/PMS system offer an approach in organic pollutant wastewater treatment since it has great advantages of high removal efficiency, conducting under neutral conditions, energy-saving and avoiding the common issues in traditional Fenton reactions.
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