纤维素
纺纱
材料科学
流变学
化学工程
蛋白质丝
粘度
衍生工具(金融)
高分子化学
化学
有机化学
复合材料
金融经济学
工程类
经济
作者
Xin Bao,Chunhong Wang,Zhenyu Zhang,Qinghua Cao,Fei Liu,Jing Chen,Chuanzhi Zhang,Haining Na,Jie Zhu
标识
DOI:10.1016/j.carpta.2021.100099
摘要
In this article, three kinds of cellulose carbonated derivatives are synthesized by modifying cellulose with alkyl halides (namely bromopropane, benzyl bromide and bromomethyl cyclopropane) in DBU/DMSO/CO2 system. The wet spinnability and filament properties of the obtained cellulose carbonated derivatives are investigated. Through rheological analysis, the solutions of various cellulose carbonated derivative in Newtonian fluid state can show good wet spinnability. Filaments with smooth surface and uniform morphology can be obtained from the solution with viscosity over 0.07Pa•s. The cellulose carbonated derivatives in the filament show similar in tight orderly rows. Among them, the cellulose propyl carbonated derivative filament exhibits the highest mechanical properties and heat resistance. By using of DBU/DMSO/CO2 system, the wet spinning and key control condition of cellulose carbonated derivatives are combined to achieve for the formation of filament with uniform morphology.
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