石墨烯
电化学气体传感器
抗坏血酸
微分脉冲伏安法
材料科学
氧化物
电化学
电极
循环伏安法
化学工程
纳米技术
化学
冶金
食品科学
工程类
物理化学
作者
Xiaoya Liu,Enbo Shangguan,Jing Li,Sashuang Ning,Litan Guo,Quanmin Li
标识
DOI:10.1016/j.msec.2016.09.034
摘要
In this paper, FeS nanoparticles anchored on reduced graphene oxide (rGO) nanosheets are synthesized via a facile direct-precipitation method. For the first time, a novel electrochemical sensor is developed based on FeS/rGO nanosheets modified glassy carbon electrode (GCE). It has been proved that the resultant FeS/rGO/GCE sensor is very suitable for the individual and simultaneous measurement of dopamine (DA) and acetaminophen (AC) and delivers excellent anti-interference ability to ascorbic acid (AA) and uric acid (UA). Under optimum conditions with differential pulse voltammetry method, a broad linear response versus the concentrations of DA and AC has been observed in the ranges of 2.0 to 250.0μM and 5.0 to 300.0μM, respectively. The detection limits for DA and AC are 0.098μM and 0.18μM, respectively. Furthermore, the as-obtained sensor has been successfully utilized in real samples and satisfactory results have been achieved. Consequently, by virtue of its outstanding electrocatalytic activity, excellent sensitivity, and long time stability, the as-obtained FeS/rGO modified electrode can be considered as a new promising DA and AC sensor.
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