Preparation of Ti4O7/h‐BN self‐supported ceramic photoelectrode and its photoelectrocatalytic performance for water purification

Abstract The construction of high‐efficiency self‐supported ceramic photoelectrode based on ideal semiconductor materials is essential for achieving effective degradation of pollutants by photoelectrocatalysis (PEC) technology. Herein, a Ti 4 O 7 /h‐BN composite ceramic photoelectrode with a unique microstructure was fabricated by a step‐by‐step calcination process and used in PEC water pollution remediation. The PEC activity of Ti 4 O 7 ceramic photoelectrode could be enhanced by introducing hexagonal boron nitride (h‐BN) nanoparticles on the surface. The most optimized Ti 4 O 7 /h‐BN photoelectrode exhibited the decolorization rate of active brilliant blue KN‐R at about 97.79% in 30 min. The PEC activities could remain stable during five degradation cycles. The excellent photoelectrocatalytic performance of Ti 4 O 7 /h‐BN ceramic photoelectrode could be attributed to the low Tafel slope, low charge transfer resistance, large electrochemical active area, and excellent photo‐generated carrier separation efficiency. A type‐II heterojunction was formed between the Ti 4 O 7 and h‐BN, which caused more effective carrier separation and enhanced the generation of dominant active species •O 2− and h + . This work provided a mature synthesis strategy of Ti 4 O 7 /h‐BN self‐supported ceramic photoelectrodes with excellent practical application prospects to achieve superior PEC performance for water purification.