Boosting(机器学习)
氢
兴奋剂
材料科学
碱土金属
海水
无机化学
二进制数
化学工程
化学
冶金
光电子学
有机化学
数学
算术
机器学习
海洋学
工程类
地质学
计算机科学
金属
作者
Jun Zhu,Jing‐Qi Chi,Xuanyi Wang,Tong Cui,Lili Guo,Bin Dong,Xiaobin Liu,Lei Wang
出处
期刊:Nano Energy
[Elsevier]
日期:2024-03-01
卷期号:121: 109249-109249
标识
DOI:10.1016/j.nanoen.2023.109249
摘要
Seawater electrolysis still faces harsh challenges especially at elevated current densities, which has to be ensured by highly-efficient and stable electrocatalyst. Recently, strategy involving hydrogen spillover between metal clusters and carriers has emerged as a means to enhance the hydrogen evolution reaction (HER) efficiency. In this study, we present a heterogeneous Ru/F-FeCoOOH catalyst to dissect the mechanism of hydrogen spillover between these two constituents. The DFT calculations and in-situ Raman analysis confirm the spillover of hydrogen species (H*) from Ru to F-FeCoOOH carrier. Furthermore, the introduction of F-doping narrows the work function disparity between the Ru metal and the F-FeCoOOH carrier, fostering a milieu that curtails interface H* capture and augments the potential for interface hydrogen spillover. Moreover, in-situ electrochemical impedance spectroscopy (EIS) and kinetic isotope effects (KIEs) corroborate that Ru/F-FeCoOOH exhibits extensive H* adsorption coverage and hydrogen transfer influences reaction rates. Leveraging the hydrogen spillover mechanism, the resultant Ru/F-FeCoOOH heterogeneous catalyst manifests a low overpotential of 260 mV at 2 A cm−2 and with long-term stability at least for 400 h in alkaline seawater.
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