Experimental demonstration of five-intensity measurement-device-independent quantum key distribution over 442 km

Decoy-state measurement-device-independent quantum key distributions (MDI-QKD) can remove all the loopholes of detection devices and establish secure keys using weak coherent sources. To further extend the secure distance and enhance the key rate, Chau proposed a novel framework for decoy-state MDI-QKD that supports an arbitrary number of intensities and investigated its performance in detail [H. F. Chau, Phys. Rev. A 102, 012611 (2020)]. Here, we experimentally demonstrate its one kind, i.e., the five-intensity MDI-QKD protocol, and achieve a positive key rate over 442 km of ultralow-loss optical fibers. Our results verify that the five-intensity protocol outperforms four-intensity protocols in terms of both distance and key rate, setting a record distance for typical MDI-QKD.