A review on polyester and polyester-amide thin film composite nanofiltration membranes: Synthesis, characteristics and applications

Nanofiltration (NF) membranes have been widely used in various fields including water treatment and other separation processes, while conventional thin film composite (TFC) membranes with polyamide (PA) selective layers suffer the problems of fouling and chlorine intolerance. Due to the abundant hydrophilic hydroxyl groups and ester bonds free from chlorine attack, the TFC membranes composed of polyester (PE) or polyester-amide (PEA) selective layers have been proven to possess enhanced anti-fouling properties and superior chlorine resistance. In this review, the research progress of PE and PEA nanofiltration membranes is systematically summarized according to the variety of hydroxyl-containing monomers for membrane fabrication by the interfacial polymerization (IP) reaction. The synthesis strategies as well as the mechanisms for tailoring properties and performance of PE and PEA membranes are analyzed, and the membrane application advantages are demonstrated. Moreover, current challenges and future perspectives of the development of PE and PEA nanofiltration membranes are proposed. This review can offer guidance for designing high-performance PE and PEA membranes, thereby further promoting the efficacy of nanofiltration.