同音
旋转交叉
自旋态
配体(生物化学)
四面体
亚胺
咪唑
自旋跃迁
自旋(空气动力学)
金属
化学物理
化学
立体化学
物理
热力学
结晶学
无机化学
有机化学
受体
催化作用
生物化学
作者
Jie-Yu Zheng,Larissa K. S. von Krbek,Tanya K. Ronson,Jonathan R. Nitschke
标识
DOI:10.1002/anie.202212634
摘要
Spin-crossover (SCO) metal-organic cages capable of switching between high-spin and low-spin states have the potential to be used as magnetic sensors and switches. Variation of the donor strength of heterocyclic aldehyde subcomponents in imine-based ligands can tune the ligand field for a FeII center, which results in both homoleptic and heteroleptic cages with diverse SCO behaviors. The tetrahedral SCO cage built from 1-methyl-1H-imidazole-2-carbaldehyde is capable of encapsulating various guests, which stabilize different cage spin states depending on guest size. Conversely, the SCO tetrahedron exhibits different affinities for guests in different spin states, which is inferred to result from subtle structural differences of the cavity caused by the change in metal center spin state. Examination of SCO thermodynamics across a series of host-guest complexes enabled sensitive probing of guest fit to the host cavity, providing information complementary to binding-constant determination.
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