An Unconventional Redox‐Neutral Regioselective Iodoamination of Allenamides

Abstract A novel unconventional redox‐neutral regioselective iodoamination of allenamides was developed. In the absence of metal catalyst, base and oxidant, the selective iodoamination of allenamides was achieved by using iodide salt in combination with morpholine/imidazole. The Iodide‐substituted Z ‐enamides were synthesized under mild reaction conditions, and the products were stable and highly amenable to further modification.