化学
试剂
亲核细胞
热情
亲脂性
组合化学
纳米技术
有机化学
催化作用
心理学
社会心理学
材料科学
作者
Ya‐Feng Si,Pingping Tang
标识
DOI:10.1002/cjoc.202300093
摘要
Comprehensive Summary The trifluoromethoxy functional group has received increasing attention in recent years due to its distinctive properties such as good metabolic stability, appropriate lipophilicity and special electrical properties. Thus, the development of new reagents and new strategies of direct trifluoromethoxylation are attracting the enthusiasm of many fluorine chemical workers. At present, nucleophilic and radical trifluoromethoxylating reagents have made major breakthroughs, greatly promoting the development of trifluoromethoxy chemistry. This review is mainly divided into two parts: nucleophilic and radical types, focusing on the development history, characteristics and applications of various trifluoromethoxylating reagents.
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