电致发光
发光
有机发光二极管
材料科学
光致发光
量子效率
磷光
荧光
紫外线
光电子学
二极管
光学
纳米技术
物理
图层(电子)
作者
Letian Xu,Hao Liu,Xiaoluo Peng,Pingchuan Shen,Ben Zhong Tang,Zujin Zhao
出处
期刊:Angewandte Chemie
[Wiley]
日期:2023-02-24
卷期号:62 (20): e202300492-e202300492
被引量:63
标识
DOI:10.1002/anie.202300492
摘要
Abstract Circularly polarized electroluminescence (CP‐EL) is generally produced in organic light‐emitting diodes (OLEDs) based on special CP luminescent (CPL) materials, while common achiral luminescent materials are rarely considered to be capable of direct producing CP‐EL. Herein, near ultraviolet CPL materials with high photoluminescence quantum yields and good CPL dissymmetry factors are developed, which can induce blue to red CPL for various achiral luminescent materials. Strong near ultraviolet CP‐EL with the best external quantum efficiencies ( η ext s) of 9.0 % and small efficiency roll‐offs are achieved by using them as emitters for CP‐OLEDs. By adopting them as hosts or sensitizers, commercially available yellow‐orange achiral phosphorescence, thermally activated delayed fluorescence (TADF) and multi‐resonance (MR) TADF materials can generate intense CP‐EL, with high dissymmetry factors and outstanding η ext s (30.8 %), demonstrating a simple and universal avenue towards efficient CP‐EL.
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