Magnetite embedded κ-carrageenan-based double network nanocomposite hydrogel with two-way shape memory properties for flexible electronics and magnetic actuators

Shape memory hydrogels attract increasing attention as flexible strain sensors due to their shape recovery property that can improve the lifetime of the sensor. Herein, we have designed a magnetic shape memory hydrogel based on Fe3O4 nanoparticles, carrageenan, and poly (acrylamide-co-acrylic acid) with self-adhesive and conductive properties. The resulting double network hydrogel showed promising actuator and strain sensor applications. Electrical conductivity was observed in this hydrogel without using additional ions. The presence of magnetite nanoparticles increased the tensile strength and temporary shape fixity ratio to around 6.5 MPa and 94.3 %, respectively. The excellent cantilever and catheter-like behavior of the hydrogels were illustrated through magnetic routing by an external magnet. Also, these hydrogels demonstrated suitable performance in the 500 cycles strain sensing tests before and after their initial shape recovery.