联氨(抗抑郁剂)
材料科学
微晶
纳米片
水合物
化学工程
纳米材料
脱氢
纳米技术
多孔性
燃料电池
催化作用
复合材料
有机化学
化学
冶金
工程类
色谱法
作者
Zhao Fang,Siyang Nie,Liang Wu,Qiang Yuan,Xun Wang
标识
DOI:10.1002/adma.202303672
摘要
Ultrathin 2D nanomaterials have attracted extensive attention due to their fascinating applications in sustainable and clean-energy-related devices, but obtaining ultrathin 2D multimetallic polycrystalline structures with large lateral dimensions remains a challenge. In this study, ultrathin 2D porous PtAgBiTe and PtBiTe polycrystalline nanosheets (PNSs) are obtained via a visible-light-photoinduced Bi2 Te3 -nanosheet-mediated route. The PtAgBiTe PNSs are assembled by sub-5 nm grains with widths beyond 700 nm. Strain and ligand effects originating from the porous, curly polycrystalline structure endow the PtAgBiTe PNSs with robust hydrazine hydrate oxidation reaction activity. Theoretical research demonstrates that the modified Pt activates the N-H bonds in N2 H4 during the reaction, and strong hybridization between Pt-5d and N-2p facilitates dehydrogenation while reducing energy consumption. The peak power densities of the PtAgBiTe PNSs in actual hydrazine-O2 /air fuel cell devices are boosted to 532.9/315.9 mW cm-2 , while those of the commercial Pt/C are 394.7/157.9 mW cm-2 . This work provides a strategy not only for preparing ultrathin multimetallic PNSs but also for finding promising electrocatalysts for actual hydrazine fuel cells.
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