Heavy metal deposition dynamics under improved vegetation in the middle reach of the Yangtze River

Estuarine heavy metal deposition processes in tributaries can reflect the environmental changes in the basin and the contribution of tributaries to the pollution of downstream lakes. The dynamic processes of heavy metal deposition in two major tributaries of the middle reaches of the Yangtze River were explored using sediment cores. The relationships between heavy metals (HMs) and various physicochemical properties were analyzed using Pearson correlation analysis. The sediment chronological sequences were determined using Pb isotope dating, and the sediment fluxes of heavy metals were calculated. The differences in the driving factors of the two watersheds were analyzed using redundancy analysis. The results showed that heavy metal in both sediment cores were significantly higher than the corresponding background values and showed a relatively stable trend from deep to shallow, with Cd being the most exceeded heavy metal in both tributaries. The average sediment deposition rate was 1.31 cm/year. The Pearson correlation analysis (PCA) results between the HMs indicated similar sources, and the correlation analysis between HM and environmental variables showed that the HMs in both cores, especially Cu and Cr, were significantly correlated with phosphorus, suggesting a synergistic loss of HMs and P. Heavy metal deposition and the normalized difference vegetation index (NDVI) in watersheds showed a negative correlation. This negative correlation is more pronounced in watersheds with higher vegetation cover, where heavy metal deposition is more driven by natural factors. The redundancy analysis (RDA) results indicated that the transport of Cd and Cu was influenced by precipitation and runoff. Heavy metal deposition processes in lake estuaries under improved terrestrial vegetation show the historical contribution of tributaries to lakes, which is important for studying pollution and ecological restoration in watersheds.