Boron‐Catalyzed Graphitization Carbon Layer Enabling LiMn0.8Fe0.2PO4 Cathode Superior Kinetics and Li‐Storage Properties

The poor electrode kinetics and low conductivity of the LiMn_0.8 Fe_0.2 PO₄ cathode seriously impede its practical application. Here, an effective strategy of boron-catalyzed graphitization carbon coating layer is proposed to stabilize the nanostructure and improve the kinetic properties and Li-storage capability of LiMn_0.8 Fe_0.2 PO₄ nanocrystals for rechargeable lithium-ion batteries. The graphite-like BC₃ is derived from B-catalyzed graphitization coating layers, which can not only effectively maintain the dynamic stability of the LiMn_0.8 Fe_0.2 PO₄ nanostructure during cycling, but also plays an important role in enhancing the conductivity and Li⁺ migration kinetics of LiMn_0.8 Fe_0.2 PO₄ @B-C. The optimized LiMn_0.8 Fe_0.2 PO₄ @B-C exhibits the fastest intercalation/deintercalation kinetics, highest electrical conductivity (8.41 × 10^-2 S cm^-1 ), Li⁺ diffusion coefficient (6.17 × 10^-12 cm² s^-1 ), and Li-storage performance among three comparison samples (B-C0, B-C6, and B-C9). The highly reversible properties and structural stability of LiMn_0.8 Fe_0.2 PO₄ @B-C are further proved by operando XRD analysis. The B-catalyzed graphitization carbon coating strategy is expected to be an effective pathway to overcome the inherent drawbacks of the high-energy density LiMn_0.8 Fe_0.2 PO₄ cathode and to improve other cathode materials with low-conductivity and poor electrode kinetics for rechargeable second batteries.